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柯贤胜 |
教授,博士生导师,理学博士(北京大学),博士后(美国得州大学奥斯汀分校) |
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通信地址:北京市新街口外大街19号化学学院 |
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邮编:100875 |
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电子邮箱:kexiansheng@bnu.edu.cn |
研究领域和兴趣
卟啉,纳米石墨烯,π-共轭功能分子,分子碳材料,超分子化学
招生信息
每年招收博士生1-2名,硕士生1-2名,欢迎热爱科研、工作认真、勤于思考、积极向上的同学加入。同时招聘博士后1-2名,具有共轭分子和金属配合物的合成经验,以及熟悉常见光谱的有机化学和无机化学背景者优先。
代表性论文
1.Haodan He+, Dohun Gwak+, Zhaohui Zong, Taeyeon Kim, * and Xian-Sheng Ke*. Dynamic Double Carbaporphyrin-Fused Nanographene: Facile Monolayer and Persistent Bilayer Switching. J. Am. Chem. Soc. 2026, DOI:10.1021/jacs.5c22919.
2. Zhaohui Zong, Haodan He, Mengdi Huang, Zhe Liu, Ningchao Liu, Shengfa Ye,* and Xian-Sheng Ke*. Doping a Nanographene with a Formal NiIV Center. J. Am. Chem. Soc. 2026, 148, 3472–3480.
3. Haodan He, Jaehyeok Ryu, Zhaohui Zong, Jiyeon Lee, Tae Hun Heo, Juwon Oh*, Jiwon Kim*, Jonathan L. Sessler* and Xian-Sheng Ke*. Nanographene-Oxy Radical Stabilized by a Carbaporphyrin Framework. J. Am. Chem. Soc. 2025, 147, 29602–29610.
4. Zhaohui Zong, Xiaotong Zhang, Ningchao Liu, Sang Mok Jung, Juwon Oh and Xian-Sheng Ke*. Iso-Dibenzo[g,p]chrysene-Fused Bis-Dicarbaporphyrin: Pd Coordination-Induced Global Aromaticity and Stabilization of Double In-Plane Pd(IV) Cations. J. Am. Chem. Soc. 2025, 147, 12777–12785.
5. Haodan He, Jiyeon Lee, Zhaohui Zong, Ningchao Liu, Yoona Noh, Vincent M. Lynch, Juwon Oh*, Jiwon Kim*, Jonathan L. Sessler* and Xian-Sheng Ke*. Precisely metal doped nanographenes via a carbaporphyrin approach. Nat. Commun. 2025, 16, 1534.
6. Ningchao Liu+, Yoonji Choi+, Zhaohui Zong, Tianming Feng, Taeyeon Kim* and Xian-Sheng Ke*. BODIPY-Cycloparaphenylene Nanorings CCS Chem. 2025, 7, 3650–3663.
7. Zhaohui Zong+, Xiaotong Zhang+, Zhe Liu, Guangliu Ran, Wenkai Zhang* and Xian-Sheng Ke*. An internally linked dibenzihexaphyrin. Sci. China Chem. 2025 68, 3108-3115.
8. Haodan He, Jiyeon Lee, Zhaohui Zong, Kyeong Mo Lim, Jaehyeok Ryu, Juwon Oh*, Jiwon Kim*, Jonathan L. Sessler* and Xian-Sheng Ke*. Precise Internal Postsynthetic Oxygen-doping of Metallonanographenes. Precis. Chem. 2025, 3, 456-462
9. Haodan He, Jiyeon Lee, Zhaohui Zong, Jiwon Kim, Vincent M. Lynch, Juwon Oh*, Dongho Kim*, Jonathan L. Sessler* and Xian-Sheng Ke*, A Janus Carbaporphyrin Pseudo-Dimer. Nat. Commun. 2024, 15, 2913.
10. Haodan He+, Yu Jin Lee+, Zhaohui Zong, Ningchao Liu, Vincent M. Lynch, Jinseok Kim, Juwon Oh*, Dongho Kim*, Jonathan L. Sessler*, and Xian-Sheng Ke*, Nanographene-Fused Expanded Carbaporphyrin Tweezers. J. Am. Chem. Soc. 2024, 146, 543-551.
11. Haodan He, Seokwon Lee, Ningchao Liu, Xiaotong Zhang, Yuying Wang, Vincent M. Lynch, Dongho Kim*, Jonathan L. Sessler*, and Xian-Sheng Ke*, Cyclic Carbaporphyrin Arrays. J. Am. Chem. Soc., 2023, 145, 3047-3054.
12. Yuying Wang+, Xian-Sheng Ke*+, Seokwon Lee, Seongsoo Kang, Vincent M. Lynch, Dongho Kim*, and Jonathan L. Sessler*, Pyrene-Bridged Expanded Carbaporphyrin Nanobelts. J. Am. Chem. Soc., 2022, 144, 9212-9216. (Front Cover)
13. Xian-Sheng Ke, Taeyeon Kim, Qing He, Vincent M. Lynch, Dongho Kim* and Jonathan L. Sessler*, Three-Dimensional Fully Conjugated Carbaporphyrin Cage. J. Am. Chem. Soc., 2018, 140, 16455-16459.
14. Xian-Sheng Ke+, Yongseok Hong+, Vincent M. Lynch, Dongho Kim* and Jonathan L. Sessler*, Metal-Stablized Quinoidal Dibenzo[g,p]chrysene-Fused Bis-dicarbacorrole System. J. Am. Chem. Soc., 2018, 140, 7579-7586.
15. Xian-Sheng Ke, Yongseok Hong, Peiyu Tu, Qing He, Vincent M. Lynch, Dongho Kim* and Jonathan L. Sessler*, Hetero Cu(III)-Pd(II) Complex of a Dibenzo[g,p]chrysene-Fused Bis-dicarbacorrole with Stable Organic Radical Character. J. Am. Chem. Soc., 2017, 139, 15232–15238.
16. Xian-Sheng Ke+, Taeyeon Kim+, Vincent M. Lynch, Dongho Kim* and Jonathan L. Sessler*, Flattened Calixarene-Like Cyclic BODIPY Array: A New Photosynthetic Antenna Model. J. Am. Chem. Soc., 2017, 139, 13950-13956.
17. Xian-Sheng Ke, Taeyeon Kim, James T. Brewster II, Vincent M. Lynch, Dongho Kim* and Jonathan L. Sessler*, Expanded Rosarin: A Versatile Fullerene (C60) Receptor. J. Am. Chem. Soc., 2017, 139, 4627–4630.
18. Xian-Sheng Ke, Hongmei Zhao, Xiaoran Zou, Yingying Ning, Xin Cheng, Hongmei Su* and Jun-Long Zhang*, Fine-Tuning of β-Substitution to Modulate the Lowest Triplet Excited States: A Bioinspired Approach to Design Phosphorescent Metalloporphyrinoids. J. Am. Chem. Soc., 2015, 137, 10745-10752.
19. Xian-Sheng Ke, Yi Chang, Jia-Zhen Chen, Jiangwei Tian, John Mack, Xin Cheng, Zhen Shen* and Jun-Long Zhang*, Porphodilactones as Synthetic Chlorophylls: Relative Orientation of β-Substituents on a Pyrrolic Ring Tunes NIR Absorption. J. Am. Chem. Soc., 2014, 136, 9598-9607.